
Mastering the Chemistry
For Polyester and Vinylester resins, the «hardener» is actually a catalyst called MEKP (Methyl Ethyl Ketone Peroxide). Unlike epoxy (which has a fixed ratio like 2:1), MEKP is added in small percentages (1% to 2%) to initiate the cure based on environmental conditions.
Calculating the Ratio
The standard range is 1.5% to 2% by weight.
# Example Calculation
Resin_Weight = 1000 # grams (1 kg)
Target_Percentage = 0.015 # 1.5%
Catalyst_Needed = Resin_Weight * Target_Percentage
# Result: 15 grams (or approx 15 ml) of MEKP
Rule of Thumb: At 25°C (77°F), use 1.5%. If it’s colder, increase to 2%. If it’s very hot, reduce to 1%.
Consequences of Improper Mixing
| Scenario | Cause | Result |
|---|---|---|
| Under-Catalyzation | Part remains sticky/tacky forever. Will not cure. | |
| Over-Catalyzation | > 2.5% MEKP | Part overheats, cracks, warps, and becomes brittle. |
| Poor Mixing | Not stirred enough | Patchy cure with soft spots and brittle spots. |
Safety Note: MEKP is an organic peroxide. It is extremely dangerous to eyes. Never mix MEKP directly with Cobalt promoter (an accelerator often pre-mixed in resin) as it can explode. Since most resins are «pre-promoted,» just add MEKP to the resin.